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The allowed rotational energy levels of a rigid hetero-nuclear diatomic molecule are expressed as εJ = BJ (J + 1), where B is the rotational constant and J is a rotational quantum number.
In a system of such diatomic molecules of reduced mass μ, some of the atoms of one element are replaced by a heavier isotope, such that the reduced mass is changed to 1.05μ. In the rotational spectrum of the system, the shift in the spectral line, corresponding to a transition J = 4 → J = 5, is
In the microwave spectrum of identical rigid diatomic molecules, the separation between the spectral lines is recorded to be 0.7143 cm-1. The moment of inertia of the molecule, in kg-m2 is
Read the following passage carefully and then choose the right word to complete the sentence that follows. Rockets are very expensive as it can be used only once. Appled scientists have therefore develped a reusable space craft called a space shuttle which takes off like a rocket; however, does no get destroyed as it returns to earth. It can also be used to lunch satellired into space, retrieve them from space if any repairing os required and allow around 8 scientists to crryout experiments in space. The space shuttle does not get.
In a diatomic molecule, the inter-nuclear separation of the ground and first excited electronic state are the same as shown in the figure. If the molecule is initially in the lowest vibrational state of the ground state, then the absorption spectrum will appear as
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Consider the pure rotational spectrum of a diatomic rigid rotor. The separation between two consecutive lines $$\Delta \overline v $$  in the spectrum
Three consecutive absorption lines at 64.275 cm-1, 77.130 cm-12 and 89.985 cm-1 have been observed in a microwave spectrum for a linear rigid diatomic molecule. The moments of inertia $${I_A}$$ and $${I_B}$$ are ($${I_A}$$ is with respect to the bond axis passing through the centre of mass and $${I_B}$$ is with respect to an axis passing through the centre of mass and perpendicular to bond axis)
Ten fabrics of different colors are displayed on ten racks in a cloth store. The racks are placed one after another and numbered consecutively from one to ten. Each rack contains fabric of a single color. One fabric is green , two fabrics are brown , three fabrics are purple and remaining four fabrics are red. If a purple fabric is on rack two and red fabrics are on racks three and four , the green fabric must be on which of the following racks?
In a three-digit number, the digit in the unit's place is 75% of the digit in the ten's place. The digit in the ten's place is greater than the digit in the hundred's place by 1. If the sum of the digits in the ten's place and the hundred's place is 15. What is the number ?
At room temperature, the rms speed of the molecules of a certain diatomic gas is found to be 1920ms-1. Which is the gas?
From the following options, choose the heteronuclear diatomic molecules which are paramagnetic in nature?