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According to Raoult's law, "The vapor pressure exerted by component in a solution is proportional to the mole fraction of that component." Raoult's law is not applicable under the following assumption/condition.
Air is to be heated by condensing steam. Two heat exchangers are available (i) a shell and tube heat exchanger and (ii) a finned tube heat exchanger. Tube side heat transfer area are equal in both the cases. The recommended arrangement is

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