Bissoy.com
Doctors Medicines MCQs Q&A

Electrophilic substitution of aniline with bromine in presence of gacial acetic acid gives which of the following?

Electrophilic substitution of aniline with bromine in presence of gacial acetic acid gives which of the following? Correct Answer 4-bromo aniline

In water,bromine is ionised up to greater extent to form large number of bromonium ions.Hence Br+ ions attack on aniline from either side to form 2,4,6,-tribromoaniline. In order to obtain monobromo aniline, reaction is carried out in presence of acetic acid. In glacial acetic acid, bromine is ionised to lesser extent and hence relatively less number of bromonium ions are formed.Thus interference of water is ceased.

Related Questions

Solution-1 containing 30% acetic acid and 20% nitrogen at the rate F combines with Solution-2 containing 20% acetic acid and 10% nitrogen at the rate D and Solution-3 containing 10% acetic acid and 30% nitrogen at the rate N the product formed contains 20% acetic acid at the rate P, what is the percentage of nitrogen in product?
Solution-1 containing 30% acetic acid and 20% nitrogen at the rate F combines with Solution-2 containing 20% acetic acid and 10% nitrogen at the rate D and Solution-3 containing 10% acetic acid and 30% nitrogen at the rate N the product formed contains 20% acetic acid at the rate 10 Kg/min, what is the percentage of nitrogen in product?
Solution-1 containing 30% acetic acid and 100% nitrogen at the rate 10 Kg/min combines with Solution-2 containing 20% acetic acid and 10% nitrogen at the rate 20 Kg/min and Solution-3 containing 10% acetic acid and 30% nitrogen at the rate 30 Kg/min the product formed contains 20% acetic acid, what is the percentage of nitrogen in product?
Solution-1 containing 30% acetic acid and 20% nitrogen at the rate 10 Kg/min combines with Solution-2 containing 20% acetic acid and 10% nitrogen at the rate 20 Kg/min and Solution-3 containing 10% acetic acid and 30% nitrogen at the rate N the product formed contains 20% acetic acid at the rate P, what is the percentage of nitrogen in product?
A batch of 20% of Acetic acid is prepared by mixing the Acetic acid of two containers A and B. A (400 kg) contains 80% of Acetic acidand B contains 15% of Acetic acid. 9. How much kg of acid is prepared?
Solution-1 containing 10% nitric acid and 20% acetic acid at the rate F combines with Solution-2 containing 20% nitric acid and 10% acetic acid at the rate D, the product formed contains 30% nitric acid and 20% acetic acid at the rate P, how many independent equations containing F, D, and P are possible?
Solution-1 containing 10% hydrochloric acid and 20% acetic acid at the rate F combines with Solution-2 containing 20% hydrochloric acid and 30% acetic acid at the rate D, the product formed contains 20% hydrochloric acid and 30% acetic acid at the rate P, how many independent equations containing F, D, and P are possible?
In a batch process, the reaction takes place in the presence of an acid medium. The acid is drained from the reaction vessel at the rate of 15ml/s as a result of the density difference of the acid from the reacting component. To avoid wastage of acid, it is recycled to an acid tank which has 1000 L capacity. The acid drained from the reaction vessel, picks up 50 g/L solids from the reactor. Acid is fed once again to the process from acid tank. When the process is started, the acid is almost pure in the tank as a result of filtration. As the reaction proceeds, acid in the tank gets more and more contaminated with the solids. The concentration of the solids should not exceed 100 g/L from the process point of view. The batch time is 16h. Estimate whether the concentration of the solids will exceed 100g/L during the batch reaction.
The depression of freezing point of a solution of acetic acid in benzene is – 0.2°C. If the molality of acetic acid is 0.1 m, then find the ratio of the normal mass to the abnormal mass. (Assume Kf of acetic acid = 4.0°C m-1)
Solution-1 containing 40% acetic acid and 20% carbon dioxide at the rate F combines with Solution-2 containing 20% acetic acid and 40% carbon dioxide at the rate D, the product formed contains 30% acetic acid at the rate P, what is the percentage of carbon dioxide in product?